The unique surface properties and the ability to surface engineer nanocrystalline structures renders these materials to be ideal candidates for use in corrosion, catalysis and energy conversion devices. This course deals with the fabrication of materials suitable for use as protective coatings, and their specific exploitation in fields of hydrogen technologies (electrolysis, storage, and fuel cells) linked to renewables. These new devices are poised to have major impacts on power generation utilities, the automotive sector, and society at large. The differences in observed electrochemical behavior between amorphous, nanocrystalline and polycrystalline solid materials will be discussed in terms of their surface structure and surface chemistry. A major team design project along with demonstrative laboratory exercises constitutes a major portion of this course.